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- W2950983364 abstract "Treatment of the tricarbonyl(eta 6-o-trimethylsilylbenzaldehyde)chromium (O) complex with cyclic silyl enol ether species under the Mukaiyama condition resulted in highly stereoselective formation of syn-aldol products, whereas the aldol reaction with O-silyl ketene O,S-acetals afforded the corresponding anti-products in a highly stereoselective manner. The tricarbonyl(eta 6-o-trimethylsilyl-benzaldehyde)chromium(O) complex has also emerged as an excellent substrate for highly regio- and stereoselective construction of cis-3,5-isoxazolidine derivatives in the 1,3-dipolar cycloaddition reaction. By taking advantage of our newly developed aldol reaction, we have succeeded in highly stereocontroled syntheses of some biologically active compounds such as C-13 side chains of taxol and taxotère, the N-terminal amino acid of nikkomycin B and Bx, and antitumor styryllactones: goniofufurone, goniotriol, and goniothalenol." @default.
- W2950983364 created "2019-06-27" @default.
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- W2950983364 date "1994-01-01" @default.
- W2950983364 modified "2023-10-14" @default.
- W2950983364 title "Development of Highly Stereoselective Reactions Based on Tricarbonyl (η<SUP>6</SUP>-o-trimethylsilylbenzaldehyde)-chromium (0) Complex" @default.
- W2950983364 doi "https://doi.org/10.1248/yakushi1947.114.7_478" @default.
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