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• W2950983784 abstract "Mukaiyama-type aldol coupling of typical silyl enolates 2-4 with aryl or vinyl aldehydes and acetals was realized in the presence of 1-5 mol % of MgI(2) etherate (1) in a mild, efficient, and highly chemoselective manner. Iodide counterion, weakly coordinating peripheral ethereal ligands (Et(2)O) of Mg(II), and a noncoordinating reaction media (i.e. CH(2)Cl(2)) are among the critical factors for the unique reactivity of this catalytic system. [reaction: see text]" @default.
• W2950983784 created "2019-06-27" @default.
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• W2950983784 date "2002-09-05" @default.
• W2950983784 modified "2023-09-23" @default.
• W2950983784 title "Chemoselective Aldol Reaction of Silyl Enolates Catalyzed by MgI₂ Etherate" @default.
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• W2950983784 doi "https://doi.org/10.1021/ol026585e" @default.
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