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- W2950984805 abstract "Abstract Thioamides are unique and versatile synthetic building blocks with S, N, and α-C three adjacent nucleophile centers, however, they are rarely used as carbon nucleophiles for transition-metal-catalyzed C–C coupling reactions. This Letter describes the first Pd-catalyzed α-arylation of thioamides and demonstrated the feasibility of the application of thioamides in coupling chemistry. By the coupling process, a variety of α-arylated thioamides were prepared in moderate to good yields under mild reaction conditions, which provides an alternative way to access functionalized thioamides as well as a new synthetic transformation for thioamides. High chemoselectivity for thioamide over amide was observed in the reaction." @default.
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- W2950984805 date "2013-06-01" @default.
- W2950984805 modified "2023-09-23" @default.
- W2950984805 title "Pd-catalyzed α-arylation of thioamides" @default.
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- W2950984805 doi "https://doi.org/10.1016/j.tetlet.2013.03.114" @default.
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