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- W2950993387 abstract "Abstract Axial ligation of a variety of oxygen donors to meso -tetraphenylporphyrinatocadmium(II) [Cd(TPP)] was studied in dichloromethane (CH 2 Cl 2 ) by the spectroscopic method. Addition of oxygen donors to Cd(TPP) caused red shifts in the absorption spectrum. The magnitude of the red shift was dependent on the charge of the axial ligands. A weak relationship between the ratio of molar extinction coefficients of alpha bands to that of beta bands and the wavenumber of the Soret band was observed. Dissociation constants ( K d ) were determined for Cd(TPP)-ligand complexes. A 1:1 binding stoichiometry is found in all cases. Increasing affinity for complex formation as a function of increasing basicity is observed among a limited set of structurally similar ligands. Steric constraints also strongly influence ligand binding affinity." @default.
- W2950993387 created "2019-06-27" @default.
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- W2950993387 date "1990-01-30" @default.
- W2950993387 modified "2023-09-27" @default.
- W2950993387 title "ChemInform Abstract: Axial Ligation of Oxygen Donors to Tetraphenylporphyrinatocadmium(II)." @default.
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- W2950993387 doi "https://doi.org/10.1002/chin.199005067" @default.
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