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- W2950994834 abstract "The reaction of alkynylzinc bromides with benzyl bromides or chlorides in the presence of a catalytic amount of Pd(DPEphos)Cl2 in THF at 23 °C cleanly produces the corresponding benzylated alkynes in 73–97% yields. With 10−3 mol % of Pd(DPEphos)Cl2, the maximum turnover number of 7.1 × 104 has been observed for the formation of PhCCCH2Ph." @default.
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- W2950994834 date "2005-04-01" @default.
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- W2950994834 title "Palladium-catalyzed cross-coupling reaction of alkynylzincs with benzylic electrophiles" @default.
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- W2950994834 doi "https://doi.org/10.1016/j.tetlet.2005.02.137" @default.
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