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- W2950996537 abstract "A surprisingly practical Pd(OAc)(2) or Pd(TFA)(2)-catalyzed reductive Heck reaction between aryl iodides and alpha,beta-unsaturated ketones is described using N,N-diisopropylethylamine (DIPEA, Hunigs base) as the reductant. In general, 1 mol% of Pd(OAc)(2) is sufficient to afford good yields using electron-rich or halogen-substituted aryl iodides. Electron-deficient aryl iodides preferentially give homocoupling. Enones containing aryl or bulky substituents on the beta-carbon react smoothly, producing mainly reductive Heck product, whereas enones with alkyl substituents on the beta-carbon afford a mixture of reductive Heck and Heck product. Deuterium labeling experiments show that the reaction is a bona fide reductive Heck reaction and exclude a Heck reaction-conjugate reduction cascade." @default.
- W2950996537 created "2019-06-27" @default.
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- W2950996537 date "2016-03-01" @default.
- W2950996537 modified "2023-09-25" @default.
- W2950996537 title "ChemInform Abstract: Palladium(II) Acetate Catalyzed Reductive Heck Reaction of Enones; a Practical Approach." @default.
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- W2950996537 doi "https://doi.org/10.1002/chin.201615102" @default.
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