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- W2950999909 abstract "A detailed investigation on the effect of solvent polarity, temperature, and microwave irradiation on periselectivity in cycloaddition reactions of pentafulvenes with 3-oxidopyrylium betaine is described. The base catalyzed generation of 3-oxidopyrylium betaine in CHCl3 resulted in the exclusive formation of [6+3] adducts. With increase in solvent polarity and temperature, mixtures of [6+3] and [3+2] adducts were formed, where as under microwave irradiation, [3+2] adducts were formed exclusively. The experimental results have been rationalized on the basis of theoretical calculations." @default.
- W2950999909 created "2019-06-27" @default.
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- W2950999909 date "2013-11-01" @default.
- W2950999909 modified "2023-09-27" @default.
- W2950999909 title "Cycloaddition profile of pentafulvenes with 3-oxidopyrylium betaine: experimental and theoretical investigations" @default.
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- W2950999909 doi "https://doi.org/10.1016/j.tet.2013.09.016" @default.
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