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- W2951003456 abstract "A new ligand 2 was prepared from (+)-thiomicamine 1 and o-methoxyphenol, and its activity as an external controller of stereochemistry in enantioselective additions of methyllithium to prochiral imines 8–10 tested. The non-racemic secondary amines 11–13 were prepared in 60–90% chemical yield with the enantioselectivity ranging from 2 to 41%. 6,7-Dimethoxy-3,4-dihydroisoquinoline 8 was transformed into (+)-salsolidine 11 with an e.e. of 41%." @default.
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- W2951003456 date "1999-12-01" @default.
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- W2951003456 title "Transformation of (+)-thiomicamine into a new ligand for the enantioselective addition of methyllithium to prochiral imines" @default.
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- W2951003456 doi "https://doi.org/10.1016/s0957-4166(99)00573-x" @default.
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