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- W2951007032 abstract "Abstract The reaction of 1-acetoxy-2,7- and 2,8-enynes with triorganoindium reagents in the presence of 5 mol % palladium catalyst provides cyclic and/or acyclic substitution products depending upon substrate structure. Enynes bearing secondary acetates, quaternary centers, or heteroatoms furnish high yields of carbocyclic or heterocyclic substitution products. NMR studies show that a single trisubstituted alkene stereoisomer is formed in the reaction. A more atom-efficient procedure for the cyclization–substitution process utilizing heteroleptic indium reagents is presented." @default.
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- W2951007032 date "2006-12-01" @default.
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- W2951007032 title "Palladium-catalyzed reactions of acetoxyenynes with triorganoindium reagents" @default.
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- W2951007032 doi "https://doi.org/10.1016/j.tetlet.2006.10.043" @default.
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