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- W2951007104 abstract "The hydrogen abstraction reactions of tert-butoxyl with germane, phosphine, and trimethylsilane were studied by pyrolyzing di-t-butyl peroxide in the temperature range of 403 to 458 K. From the reported rate constant for the tert-butoxy radical decomposition in the literature, the absolute rate constants were determined from the study of competitive reaction between t-butoxy radical decomposition and hydrogen abstraction reaction. (t-BuO + RH → t-BuOH + R, where RH = GeH4, PH3, and HSiMe3)The Arrhenius parameters are found to be as follows: TextTable Text. Ea(kcal mol−1)Log A(1.mol−1s−1)t-BuO + SiHMe32.18.5t-BuO + GeH41.99.1t-BuO + PH31.49.0" @default.
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- W2951007104 date "1986-06-24" @default.
- W2951007104 modified "2023-09-23" @default.
- W2951007104 title "ChemInform Abstract: Gas Phase Kinetic Study of the Thermal Reactions of t-Butoxy Radicals with Germane, Phosphine, and Trimethylsilane" @default.
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- W2951007104 doi "https://doi.org/10.1002/chin.198625154" @default.
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