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- W2951008112 endingPage "1414" @default.
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- W2951008112 abstract "Neopentyl arenesulfonates reacted with primary alkylmagnesium halides in the presence of <TEX>$(PPh_3)_2NiCl_2$</TEX> to produce the corresponding alkylarenes. The efficiency of this coupling reaction considerably depends on the nature of catalyst and solvent. Highest yield was obtained by using three equivalents of Grignard reagent to a mixture of <TEX>$(PPh_3)_2NiCl_2$</TEX> and arenesulfonate in refluxing <TEX>$Et_2O$</TEX>. This reaction represents a novel method allowing the efficient and creative substitution of sulfur-containing groups in aromatic compounds. It also shows that the alkyloxysulfonyl group might be a suitable alternative to halides and triflate in some circumstances." @default.
- W2951008112 created "2019-06-27" @default.
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- W2951008112 date "2005-09-20" @default.
- W2951008112 modified "2023-09-23" @default.
- W2951008112 title "Nickel-Catalyzed Coupling of Arenesulfonates with Primary Alkylmagnesium Halides" @default.
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- W2951008112 doi "https://doi.org/10.5012/bkcs.2005.26.9.1410" @default.
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