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- W2951017542 abstract "The circular dichroism (CD) exciton chirality method was employed for the stereochemical assignment of the tricarballylic acid (TCA) side chains of fumonisin B(1) 1a (FB(1)). Using 2-naphthoate for chromophoric derivatization of the reduced TCA moieties, the absolute configuration was shown to be R. For additional confirmation, an optically active dihydroxy-tert-butanoate 2 related to the TCA group of fumonisin B(1) was synthesized to serve as a model compound." @default.
- W2951017542 created "2019-06-27" @default.
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- W2951017542 date "2001-05-10" @default.
- W2951017542 modified "2023-09-27" @default.
- W2951017542 title "Combined Synthetic/CD Strategy for the Stereochemical Assignment of the Tricarballylic Acid Side Chains of Fumonisin B1" @default.
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- W2951017542 doi "https://doi.org/10.1021/jo0000630" @default.
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