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• W2951031866 abstract "A family of N-methylpyrrolidinium fullerene iodide salts, possessing one (or two) solubilizing chain(s), has been synthesized. As evidenced by CV and steady-state voltammetry experiments, carried out in tetrahydrofuran (THF) solutions, these species show enhanced electron-accepting properties with respect to both the parent fulleropyrrolidines and C60. CV measurements performed at −60 °C and scan rates of 50 V/s, made possible by the use of ultramicroelectrodes, have allowed the observation, for the first time in fullerene derivatives, of six fullerene-centered reductions. Bulk electrolysis of these novel compounds, performed at the stage of the first reduction potential, generates a stable zwitterion, with both anion and cation located on the fullerene derivative." @default.
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• W2951031866 date "1998-10-29" @default.
• W2951031866 modified "2023-10-16" @default.
• W2951031866 title "Enhanced Acceptor Character in Fullerene Derivatives. Synthesis and Electrochemical Properties of Fulleropyrrolidinium Salts" @default.
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• W2951031866 doi "https://doi.org/10.1021/ja9827705" @default.
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