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- W2951036268 abstract "A literature and authors' review of influence of hydrogen absorption on the crystal structure of binary RM 2 and ternary RM 2-x M' x , R 1-x R' x Ni 2 and RM 2-x Al x , (R = Rare earth; M = Mn, Fe, Co, Ni) Laves phase compounds are presented. Majority of these compounds absorb hydrogen at pressure 0.1-0.12 MPa and room temperature preserving the crystalline state. The phases form hydrides with the amount of hydrogen up to 4.2 atoms H per formula unit (at.H/f.u.) and up to 5 at.H/f.u. at high hydrogen pressure. The unit cell volume increases under hydrogenation up to 20 % and up to 30 % at high hydrogen pressure. In many cases the doping of binary phases by the third element increases hydrogenation capacity of intermetallics under the same hydrogenation conditions. The structure of the parent compound is preserved or slightly distorted during hydrogenation." @default.
- W2951036268 created "2019-06-27" @default.
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- W2951036268 date "2009-07-15" @default.
- W2951036268 modified "2023-09-23" @default.
- W2951036268 title "Hydrogen Sorption Properties of Some RM 2-x M' x and RM 2-x Al x (R = Y, Gd, Tb, Er, Ho; M = Mn, Fe, Co, Ni) Laves Phase Ternary Compounds" @default.
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