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- W2951036995 abstract "Several MOP ligands 5 containing aryl groups at 2′ position of (R)-2-(diphenylphosphino)-1,1′-binaphthyl skeleton were prepared and used for palladium-catalyzed asymmetric hydrosilylation of cyclic 1,3-dienes 6 with trichlorosilane. Highest enantioselectivity was observed in the reaction of 1,3-cyclopentadiene (6a) catalyzed by a palladium complex (0.25 mol %) coordinated with (R)-2-(diphenylphosphino)-2′-(3,5-dimethyl-4-methoxyphenyl)-1,1′-binaphthyl (5f), which gave (S)-3-(trichlorosilyl)cyclopentene of 90% ee." @default.
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- W2951036995 date "2001-03-30" @default.
- W2951036995 modified "2023-10-10" @default.
- W2951036995 title "Modification of Chiral Monodentate Phosphine Ligands (MOP) for Palladium-Catalyzed Asymmetric Hydrosilylation of Cyclic 1,3-Dienes" @default.
- W2951036995 doi "https://doi.org/10.1002/1615-4169(20010330)343:3<279::aid-adsc279>3.0.co;2-5" @default.
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