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- W2951039782 abstract "Abstract Palladium-catalysed intramolecular asymmetric Heck reactions were performed on triflate 5 using complexes derived from BINAP and a range of oxazoline-containing phosphinamine ligands. The optimum ee obtained was 85% employing the t-butyl-substituted ferrocenyloxazoline ligand 6 . The isomer distribution of the product spirooxindoles was dependent on the ligand chosen, with the oxazoline-containing ligands showing an increased selectivity (up to 99:1) for the Δ2,3-isomer 3 compared to BINAP (optimum 75:25)." @default.
- W2951039782 created "2019-06-27" @default.
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- W2951039782 date "2003-03-25" @default.
- W2951039782 modified "2023-09-27" @default.
- W2951039782 title "A Comparative Study of Diphosphine and Phosphinamine Palladium Complexes on a New Substrate for the Intramolecular Asymmetric Heck Reaction." @default.
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- W2951039782 doi "https://doi.org/10.1002/chin.200312112" @default.
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