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- W2951040404 abstract "Manganese oxide prepared by a simple hydrothermal method is highly active and stable in both lab and quasi industrial conditions for the total oxidation of toluene, achieving total conversion at only 175 °C in the absence of water and at 150 °C in the presence of 4 mol % water. Moreover, this performance is stable for at least 6 cycles. The enhanced catalytic performance has been related to the presence of highly reactive oxygen surface species. This species are probably promoted by Mn3O4 nanoparticles with Mn3+ at the tetragonal distorted cationic sites, likely compensated by structural water at the anionic sites. The presence of structural water can be related to the formation of internal cavities/vesicles in the Mn3O4 crystalline structure." @default.
- W2951040404 created "2019-06-27" @default.
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- W2951040404 date "2019-07-01" @default.
- W2951040404 modified "2023-10-18" @default.
- W2951040404 title "Green synthesis of cavity-containing manganese oxides with superior catalytic performance in toluene oxidation" @default.
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- W2951040404 doi "https://doi.org/10.1016/j.apcata.2019.06.005" @default.
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