Matches in SemOpenAlex for { <https://semopenalex.org/work/W2951044063> ?p ?o ?g. }
Showing items 1 to 85 of
85
with 100 items per page.
- W2951044063 abstract "Silver complexes bearing trispyrazolylborate ligands (Tpx) catalyze the aziridination of 2,4-diene-1-ols in a chemo-, regio-, and stereoselective manner to give vinylaziridines in high yields by means of the metal-mediated transfer of NTs (Ts = p-toluensulfonyl) units from PhI═NTs. The preferential aziridination occurs at the double bond neighboring to the hydroxyl end in ca. 9:1 ratios that assessed a very high degree of regioselectivity. The reaction with the silver-based catalysts proceeds in a stereospecific manner, i.e., the initial configuration of the C═C bond is maintained in the aziridine product (cis or trans). The degree of regioselectivity was explained with the aid of DFT studies, where the directing effect of the OH group of 2,4-diene-1-ols plays a key role. Effective strategies for ring-opening of the new aziridines, deprotection of the Ts group, and subsequent formation of β-amino alcohols have also been developed." @default.
- W2951044063 created "2019-06-27" @default.
- W2951044063 creator A5019047795 @default.
- W2951044063 creator A5019270042 @default.
- W2951044063 creator A5028002953 @default.
- W2951044063 creator A5030445591 @default.
- W2951044063 creator A5045676433 @default.
- W2951044063 creator A5054695424 @default.
- W2951044063 creator A5086202564 @default.
- W2951044063 creator A5088884536 @default.
- W2951044063 creator A5090435377 @default.
- W2951044063 date "2014-09-25" @default.
- W2951044063 modified "2023-10-17" @default.
- W2951044063 title "ChemInform Abstract: Chemo-, Regio-, and Stereoselective Silver-Catalyzed Aziridination of Dienes: Scope, Mechanistic Studies, and Ring-Opening Reactions." @default.
- W2951044063 cites W2052774846 @default.
- W2951044063 doi "https://doi.org/10.1002/chin.201441109" @default.
- W2951044063 hasPublicationYear "2014" @default.
- W2951044063 type Work @default.
- W2951044063 sameAs 2951044063 @default.
- W2951044063 citedByCount "0" @default.
- W2951044063 crossrefType "journal-article" @default.
- W2951044063 hasAuthorship W2951044063A5019047795 @default.
- W2951044063 hasAuthorship W2951044063A5019270042 @default.
- W2951044063 hasAuthorship W2951044063A5028002953 @default.
- W2951044063 hasAuthorship W2951044063A5030445591 @default.
- W2951044063 hasAuthorship W2951044063A5045676433 @default.
- W2951044063 hasAuthorship W2951044063A5054695424 @default.
- W2951044063 hasAuthorship W2951044063A5086202564 @default.
- W2951044063 hasAuthorship W2951044063A5088884536 @default.
- W2951044063 hasAuthorship W2951044063A5090435377 @default.
- W2951044063 hasConcept C155647269 @default.
- W2951044063 hasConcept C161790260 @default.
- W2951044063 hasConcept C176933379 @default.
- W2951044063 hasConcept C178790620 @default.
- W2951044063 hasConcept C181647583 @default.
- W2951044063 hasConcept C185592680 @default.
- W2951044063 hasConcept C187921627 @default.
- W2951044063 hasConcept C2778544067 @default.
- W2951044063 hasConcept C2778652500 @default.
- W2951044063 hasConcept C2778733088 @default.
- W2951044063 hasConcept C2780378348 @default.
- W2951044063 hasConcept C59759590 @default.
- W2951044063 hasConcept C68381374 @default.
- W2951044063 hasConcept C71240020 @default.
- W2951044063 hasConceptScore W2951044063C155647269 @default.
- W2951044063 hasConceptScore W2951044063C161790260 @default.
- W2951044063 hasConceptScore W2951044063C176933379 @default.
- W2951044063 hasConceptScore W2951044063C178790620 @default.
- W2951044063 hasConceptScore W2951044063C181647583 @default.
- W2951044063 hasConceptScore W2951044063C185592680 @default.
- W2951044063 hasConceptScore W2951044063C187921627 @default.
- W2951044063 hasConceptScore W2951044063C2778544067 @default.
- W2951044063 hasConceptScore W2951044063C2778652500 @default.
- W2951044063 hasConceptScore W2951044063C2778733088 @default.
- W2951044063 hasConceptScore W2951044063C2780378348 @default.
- W2951044063 hasConceptScore W2951044063C59759590 @default.
- W2951044063 hasConceptScore W2951044063C68381374 @default.
- W2951044063 hasConceptScore W2951044063C71240020 @default.
- W2951044063 hasLocation W29510440631 @default.
- W2951044063 hasOpenAccess W2951044063 @default.
- W2951044063 hasPrimaryLocation W29510440631 @default.
- W2951044063 hasRelatedWork W2008832426 @default.
- W2951044063 hasRelatedWork W2052774846 @default.
- W2951044063 hasRelatedWork W2055445049 @default.
- W2951044063 hasRelatedWork W2056998186 @default.
- W2951044063 hasRelatedWork W2160845740 @default.
- W2951044063 hasRelatedWork W2295410858 @default.
- W2951044063 hasRelatedWork W2736305164 @default.
- W2951044063 hasRelatedWork W2949417279 @default.
- W2951044063 hasRelatedWork W2949599670 @default.
- W2951044063 hasRelatedWork W2949789156 @default.
- W2951044063 hasRelatedWork W2950149863 @default.
- W2951044063 hasRelatedWork W2950799492 @default.
- W2951044063 hasRelatedWork W2952325219 @default.
- W2951044063 hasRelatedWork W2952362107 @default.
- W2951044063 hasRelatedWork W2952785989 @default.
- W2951044063 hasRelatedWork W2952994262 @default.
- W2951044063 hasRelatedWork W2953104473 @default.
- W2951044063 hasRelatedWork W3048050005 @default.
- W2951044063 hasRelatedWork W3206102031 @default.
- W2951044063 hasRelatedWork W950074439 @default.
- W2951044063 isParatext "false" @default.
- W2951044063 isRetracted "false" @default.
- W2951044063 magId "2951044063" @default.
- W2951044063 workType "article" @default.