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- W2951046987 abstract "Sixteen Herschbach ionic Morse potential energy curves (HIMPEC) were classified using molecular ion formation M or dissociation D in a vertical transition. Two activation energies for thermal electron attachment to Cl2, Br2, and I2 are reported from a reanalysis of electron-capture detector data. The HIMPEC for the diatomic halogens and oxygen are optimized by including new experimental data. All of the halogen curves are defined by at least three data points. Two new curves for the 2Πg(1/2) states of Br2(−) and I2(−) are constructed using a lower experimental dissociation energy. New electron-capture detector data for O2 confirm multiple activation energies and electron affinities, Ea. The twelve M and twelve D curves for the 24 predicted anionic states of O2 are calculated using Ea, vertical electron affinities, activation energies, frequencies, and estimated dissociation energies. Two curves are calculated from experimental data for anions of S2, Se2, and Te2." @default.
- W2951046987 created "2019-06-27" @default.
- W2951046987 creator A5080705891 @default.
- W2951046987 date "2002-12-10" @default.
- W2951046987 modified "2023-09-25" @default.
- W2951046987 title "Semiempirical Characterization of Homonuclear Diatomic Ions: 6. Group VI and VII Anions" @default.
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- W2951046987 doi "https://doi.org/10.1021/jp0268922" @default.
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