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• W2951071169 abstract "The Mg-activation of benzal bromide 2b in DMF in the presence of carbonyl compounds 1 or imines 4 leads to epoxides 3 and N-arylaziridines 5, respectively, with acceptable isolated yields. It was found that DMF is likely involved in this process to form a nucleophilic intermediate by reaction with a first generated electrophilic carbene. Results obtained in this chemical approach are compared to those obtained using electrochemical activation, also in DMF." @default.
• W2951071169 created "2019-06-27" @default.
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• W2951071169 date "2014-01-01" @default.
• W2951071169 modified "2023-10-18" @default.
• W2951071169 title "Formation of epoxides and N-arylaziridines via a simple Mg-Barbier reaction in DMF" @default.
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• W2951071169 doi "https://doi.org/10.1016/j.tet.2013.12.016" @default.
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