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- W2951082318 abstract "The phosphate α-Sr(PO3)2 was synthesised as a single-phase crystalline powder starting from strontium carbonate and phosphorous acid at a temperature of 1150 K. α-Sr(PO3)2 crystallises in a novel structure type in which helical PO3− catena-polyphosphate ions interpenetrate a substructure of Sr2+ closely related to cubic diamond (Sr4(PO3)8, P21, Z=2, a=735.37(8), b=1868.2(2), c=735.81(8)pm, β=90.021(9)°). The catena-polyphosphate chains form helices running along [010]. Their chain-periodicity is 16 and the length of the repeating unit complies with b=1868pm, the chain stretching factor amounts to fs=0.48 and the pitch to radius ratio is ξ=2.49. The vibrational spectra of α-Sr(PO3)2 are also reported." @default.
- W2951082318 created "2019-06-27" @default.
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- W2951082318 date "2005-10-01" @default.
- W2951082318 modified "2023-10-16" @default.
- W2951082318 title "The synthesis, crystal structure and vibrational spectra of α-Sr(PO3)2 containing an unusual catena-polyphosphate helix" @default.
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- W2951082318 doi "https://doi.org/10.1016/j.solidstatesciences.2005.06.014" @default.
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