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• W2951092867 abstract "Synthesis of 2-amino-4H-chromen-4-ylphosphonates and 2-amino-4H-chromenes has been accomplished by the reaction of salicylaldehyde, malononitrile, dialkyl/diphenylphosphites catalyzed by 1,1,3,3-tetramethylguanidine (TMG) under neat conditions at room temperature. The applicability of catalytic TMG for the synthesis of 2-amino-4H-chromenes also has been described. The mild reaction conditions, simple work-up procedure, and use of TMG as an inexpensive catalyst provides an economical protocol for the preparation of important phosphorus-containing compounds." @default.
• W2951092867 created "2019-06-27" @default.
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• W2951092867 date "2013-12-01" @default.
• W2951092867 modified "2023-10-14" @default.
• W2951092867 title "Synthesis of 2-amino-3-cyano-4H-chromen-4-ylphosphonates and 2-amino-4H-chromenes catalyzed by tetramethylguanidine" @default.
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• W2951092867 doi "https://doi.org/10.1016/j.tet.2013.10.052" @default.
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