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• W2951093361 abstract "Antiferromagnetic(AFM)|ferrimagnetic(FiM) core|shell (CS) nanoparticles (NPs) of formula Co0.3Fe0.7O|Co0.6Fe2.4O4 with mean diameter from 6 to 18 nm have been synthesized through a one-pot thermal decomposition process. The CS structure has been generated by topotaxial oxidation of the core region, leading to the formation of a highly monodisperse single inverted AFM|FiM CS system with variable AFM-core diameter and constant FiM-shell thickness (∼2 nm). The sharp interface, the high structural matching between both phases, and the good crystallinity of the AFM material have been structurally demonstrated and are corroborated by the robust exchange-coupling between AFM and FiM phases, which gives rise to one among the largest exchange bias (H E) values ever reported for CS NPs (8.6 kOe) and to a strongly enhanced coercive field (H C). In addition, the investigation of the magnetic properties as a function of the AFM-core size (d AFM), revealed a nonmonotonous trend of both H C and H E, which display a maxi..." @default.
• W2951093361 created "2019-06-27" @default.
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• W2951093361 date "2016-08-01" @default.
• W2951093361 modified "2023-09-27" @default.
• W2951093361 title "ChemInform Abstract: Strongly Exchange Coupled Core|Shell Nanoparticles with High Magnetic Anisotropy: A Strategy Toward Rare-Earth-Free Permanent Magnets." @default.
• W2951093361 cites W2394729405 @default.
• W2951093361 doi "https://doi.org/10.1002/chin.201636010" @default.
• W2951093361 hasPublicationYear "2016" @default.
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