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- W2951097114 abstract "Single crystals of the layered compound K2Na[Ag(CN)2]3 exhibit a dual emission with high-energy (HE) and low-energy (LE) phosphorescence bands at 313 and 402 nm, respectively. Remarkably, the crystals exhibit optical memory, in which a new emission band with intermediate energy (IE) at 380 nm is generated upon laser irradiation (lambda ex = 266 nm) at cryogenic temperatures. The irradiated crystals reinstate their original luminescence spectrum upon heating to room temperature and then recooling. In addition to these unusual write/read/erase changes, the crystals also exhibit multistep luminescence thermochromism such that the LE/HE intensity ratio increases between 17 and 80 K but then decreases upon further heating. The unprecedented occurrence of both novel phenomena in one compound has been related to reversible photophysical changes instead of irreversible photochemical changes." @default.
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- W2951097114 date "2007-04-13" @default.
- W2951097114 modified "2023-09-24" @default.
- W2951097114 title "Optical Memory and Multistep Luminescence Thermochromism in Single Crystals of K<sub>2</sub>Na[Ag(CN)<sub>2</sub>]<sub>3</sub>" @default.
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- W2951097114 doi "https://doi.org/10.1021/ic070198p" @default.
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