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- W2951097360 abstract "A highly enantioselective carboalkoxylation of alkynes catalyzed by cationic (DTBM-MeO-Biphep)gold(I) complexes is reported. Various optically active β-alkoxyindanone derivatives were obtained in good yields with high enantioselectivities. Furthermore, this methodology was extended to the enantioselective synthesis of 3-methoxycyclopentenones. The reaction is proposed to proceed through an enantioselective cyclization of intermediates containing vinylgold(I) and prochiral oxocarbenium moieties." @default.
- W2951097360 created "2019-06-27" @default.
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- W2951097360 date "2014-01-31" @default.
- W2951097360 modified "2023-09-27" @default.
- W2951097360 title "ChemInform Abstract: Gold(I)-Catalyzed Enantioselective Carboalkoxylation of Alkynes." @default.
- W2951097360 cites W2067125034 @default.
- W2951097360 doi "https://doi.org/10.1002/chin.201407094" @default.
- W2951097360 hasPublicationYear "2014" @default.
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