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- W2951114374 abstract "Abstract The phenyldimethylsilyl to hydroxyl transformation fails in the cases where a cyclic tertiary carbon center is involved as was observed in the synthesis of phorbol C-ring models. An alternate functionality in the form of allyldimethyl silane (ADMS) is found to work well in these and other cases involving tertiary centers. With proper choice of reagents, the ADMS group can be employed as a latent alcohol in systems containing ketones, esters, arenes, and vinyl groups." @default.
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- W2951114374 date "1991-12-01" @default.
- W2951114374 modified "2023-10-14" @default.
- W2951114374 title "Synthesis of tertiary alcohols via the use of the allyldimethylsilyl moiety as a latent hydroxyl group in the Kumada-Fleming-Tamao reaction." @default.
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- W2951114374 doi "https://doi.org/10.1016/0040-4039(91)80521-7" @default.
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