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- W2951126633 abstract "anti-(Trifluoromethyl) β-amino alcohols 2 have been prepared in good yields and with 90% diastereoisomeric excess through a reaction of 1-(trifluoromethyl) epoxy ethers 3 with dimethylaluminum amide, followed by the in situ chelation-controlled stereoselective reduction of the intermediate amino ketone. The salen-mediated chiral epoxidation of 1-(trifluoromethyl) enol ether 4a led to the homochiral epoxy ethers 11a and 12a in a good enantiomeric excess. Reaction with dimethylaluminum amide followed by a reduction step provided the chiral amino alcohols 15a and 16a, respectively." @default.
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- W2951126633 date "1998-08-29" @default.
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- W2951126633 title "Stereoselective and Enantioselective Synthesis ofanti-1-(Trifluoromethyl) Amino Alcohols" @default.
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- W2951126633 doi "https://doi.org/10.1021/jo9805448" @default.
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