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- W2951132363 abstract "Thiol esters and boronic acids react to produce ketones under aerobic conditions in the presence of catalytic quantities of a CuI or CuII salt. The reaction occurs at reasonable rates between room temperature and 50 °C at neutral pH using thiol esters derived from bulky 2° amides of thiosalicylamides such as those based on N-tert-butyl-2-mercaptobenzamide. In this mechanistically unprecedented reaction system, the carbon−carbon bond formation occurs through templating of the thiol ester and the boronic acid at copper; the system is rendered catalytic in copper under the aerobic conditions." @default.
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- W2951132363 date "2008-04-29" @default.
- W2951132363 modified "2023-09-26" @default.
- W2951132363 title "ChemInform Abstract: A New Paradigm for Carbon—Carbon Bond Formation: Aerobic, Copper-Templated Cross-Coupling." @default.
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- W2951132363 doi "https://doi.org/10.1002/chin.200818072" @default.
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