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- W2951133389 abstract "Microwave irradiation promoted the intramolecular cycloaddition of 2-azidoacetamides derived from α-chiral propargylic amines, affording 1,4,5-trisubstituted triazoles 4 bearing a chiral aminomethyl side chain at C5. In contrast, for the same substrates 3a–k, Cu(I)–NHC complexes catalyzed the intermolecular cycloaddition in an unexpected desilylative fashion, leading to 1,4-disubstituted triazoles 5. This demonstrates that 1-silyl alkynes can be employed as substrates for CuAAC with a suitable coupling partner." @default.
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- W2951133389 date "2015-03-19" @default.
- W2951133389 modified "2023-09-23" @default.
- W2951133389 title "ChemInform Abstract: Microwave-Assisted or Cu-NHC-Catalyzed Cycloaddition of Azido-Disubstituted Alkynes: Bifurcation of Reaction Pathways." @default.
- W2951133389 cites W2037585333 @default.
- W2951133389 doi "https://doi.org/10.1002/chin.201514177" @default.
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