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- W2951147029 abstract "Chiral vicinal diamines, including 2-aminomethyl indolines and pyrrolidines, are useful as ligands for catalytic asymmetric reactions and are also found as important components of bioactive compounds. Herein is reported the first copper-catalyzed alkene diamination that occurs with high enantioselectivity. The substrate range is the broadest yet reported for this kind of intra-/intermolecular reaction sequence both with respect to γ-alkenyl sulfonamide substrate and external amine nucleophile. The resulting products expand the availability of substituted 2-aminomethyl indolines and pyrrolidines, privileged compounds in asymmetric catalysis and medicinal chemistry. A unique solution to a challenging oxidation problem related to copper catalyst turnover is also presented." @default.
- W2951147029 created "2019-06-27" @default.
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- W2951147029 date "2014-09-25" @default.
- W2951147029 modified "2023-09-27" @default.
- W2951147029 title "ChemInform Abstract: Copper-Catalyzed Alkene Diamination: Synthesis of Chiral 2-Aminomethyl Indolines and Pyrrolidines." @default.
- W2951147029 cites W2092024668 @default.
- W2951147029 doi "https://doi.org/10.1002/chin.201441121" @default.
- W2951147029 hasPublicationYear "2014" @default.
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