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• W2951156615 endingPage "1071" @default.
• W2951156615 startingPage "1068" @default.
• W2951156615 abstract "A gold(I)-catalyzed decarboxylative amination of allylic N-tosylcarbamates via base-induced aza-Claisen rearrangement has been developed. A variety of substituted N-tosyl allylic amines were obtained in good yield, excellent regioselectivity, and high to excellent stereoselectivity. This transformation could be performed either in H(2)O or in one pot directly from allylic alcohols and therefore represents an efficient and environmentally benign protocol for the synthesis of N-tosyl allylic amines." @default.
• W2951156615 created "2019-06-27" @default.
• W2951156615 creator A5039892697 @default.
• W2951156615 creator A5086328096 @default.
• W2951156615 date "2010-02-09" @default.
• W2951156615 modified "2023-10-06" @default.
• W2951156615 title "Gold(I)-Catalyzed Highly Regio- and Stereoselective Decarboxylative Amination of Allylic <i>N</i>-Tosylcarbamates via Base-Induced Aza-Claisen Rearrangement in Water" @default.
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• W2951156615 doi "https://doi.org/10.1021/ol100056f" @default.
• W2951156615 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/20143843" @default.
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