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- W2951161264 abstract "A new π-conjugated system, 1-isopropylidene-1H-cyclopent[a]azulene was synthesized by the base-catalyzed condensation of 1H-cyclopent[a]azulene with acetone. An isomeric 3-isopropylidene-3H-cyclopent[a]azulene was also synthesized by the reaction of 3H-cyclopent[a]azulen-3-one with dimethylketene. The condensation of fulvene did not perturb the properties of the azulene moiety as shown by the spectral data. The X-ray analysis of 3-isopropylidene-3H-cyclopent[a]azulene also indicated that this π-conjugated system was an azulene moiety slightly perturbed by the fused fulvene ring." @default.
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- W2951161264 date "1993-01-01" @default.
- W2951161264 modified "2023-09-26" @default.
- W2951161264 title "Synthesis of a Polycyclic .PI.-Conjugated System Containing an Azulene Unit by the Flash Vacuum Pyrolytic Method. IV. Synthesis and Properties of 1-Isopropylidene-1H- and 3-Isopropylidene-3H-cyclopent(a)azulene." @default.
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- W2951161264 doi "https://doi.org/10.1246/bcsj.66.245" @default.
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