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- W2951168081 abstract "Abstract 1,4-Addition of arylboronic acid to trans-β-arylenals proceeded smoothly in acetone–water (10/1) at 10–25 °C in the presence of [Pd(S,S-chiraphos)(PhCN)2](SbF6)2 (0.5 mol %), AgX (X = BF4, SbF6, 10 mol %) and aqueous 42% HBF4 to afford optically active 3,3-diarylalkanals with high enantioselectivities in a range of 86–97% ee. The protocol provided a method for short-step synthesis of optically active (+)-(R)-CDP 840." @default.
- W2951168081 created "2019-06-27" @default.
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- W2951168081 date "2007-09-18" @default.
- W2951168081 modified "2023-09-23" @default.
- W2951168081 title "Palladium(II)-Catalyzed 1,4-Addition of Arylboronic Acids to β-Arylenals for Enantioselective Syntheses of 3,3-Diarylalkanals: A Short Synthesis of (+)-(R)-CDP 840." @default.
- W2951168081 cites W2178594302 @default.
- W2951168081 doi "https://doi.org/10.1002/chin.200738086" @default.
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