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• W2951176214 abstract "In this contribution, we investigate the thermal decomposition of four pentapeptides containing a tryptophan moiety. Pentapeptides were heated at 220 °C, and the resulting reaction mixtures were investigated by HPLC coupled to high-resolution mass spectrometry and tandem mass spectrometry. A total of 95 thermal decomposition products could be observed and resolved by chromatography. In detail, we report on the structure assignment of two types of reaction products common to investigated peptides and introduce two decomposition mechanisms. Pentapeptides react with oxygen to produce hydroxyl-tryptophan derivatives. In addition, we observe the C-terminal decarboxylation of two peptides to form N-acyl tryptamine derivatives." @default.
• W2951176214 created "2019-06-27" @default.
• W2951176214 creator A5045138039 @default.
• W2951176214 creator A5058167943 @default.
• W2951176214 date "2019-06-21" @default.
• W2951176214 modified "2023-10-03" @default.
• W2951176214 title "Identification of Products from Thermal Degradation of Tryptophan Containing Pentapeptides: Oxidation and Decarboxylation" @default.
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• W2951176214 doi "https://doi.org/10.1021/acs.jafc.9b01056" @default.
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