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W2951198111 abstract "Abstract An efficient, regioselective Cu(OTf)2-catalyzed 5-exo-dig intramolecular hydroalkoxylation of 2-(ethynyl)benzyl alcohol, which provides a concise access to functionalized phthalan in high yields has been developed. A wide range of substrates possessing terminal, internal, and heteroaromatic alkynes can be efficiently transformed into the targeted phthalans. Substrates with primary, secondary, and tertiary benzyl alcohols also proceed well to produce the corresponding phthalans in good yields. Irrespective of the nature of the substrates, the cyclization follows highly selective 5-exo-dig regiochemistry when regioselectivity is an issue." @default.
W2951198111 created "2019-06-27" @default.
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W2951198111 date "2010-12-02" @default.
W2951198111 modified "2023-09-26" @default.
W2951198111 title "ChemInform Abstract: Regioselective Synthesis of Phthalans via Cu(OTf)2-Catalyzed 5-exo-Dig Intramolecular Hydroalkoxylation of 2-(Ethynyl)benzyl Alcohols." @default.
W2951198111 cites W2067121655 @default.
W2951198111 doi "https://doi.org/10.1002/chin.201052106" @default.
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