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- W2951206598 abstract "Abstract A series of new C 2 -symmetric chiral aza crown ether macrocycles 1 – 4 have been synthesized from ( S )-3-aryloxy-1,2-propanediol and ( S )-1,2-propanediol for the enantiomeric recognition of amino acid ester derivatives. These new macrocycles have been shown to be strong complexing agents for primary organic ammonium salts (with K up to 176.93 M −1 and Δ G ° up to 12.81 kJ mol −1 ) by 1 H NMR titration. These macrocyclic host exhibited enantioselective bonding toward the d -enantiomer of phenylalanine methyl ester hydrochloride with K D / K L up to 6.87 in CDCl 3 with 0.25% CD 3 OD." @default.
- W2951206598 created "2019-06-27" @default.
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- W2951206598 date "2010-03-23" @default.
- W2951206598 modified "2023-09-26" @default.
- W2951206598 title "ChemInform Abstract: Synthesis of Novel C2-Symmetric Chiral Crown Ethers and Investigation of Their Enantiomeric Recognition Properties." @default.
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- W2951206598 doi "https://doi.org/10.1002/chin.201012201" @default.
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