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- W2951223397 abstract "Allylboration of representative vinylic epoxides with allyldiethylborane (1) and (2-cyclohexenyl)dicyclohexylborane (2) affords the corresponding 1,2- and 1,4-addition products. cis-1, 2-Addition is favored in the reaction of 1 with 3, 4-epoxycycloalkenes of six- to eight-membered rings. 3, 4-Epoxycyclopentene (3a) and 5,5-dimethyl-3,4-epoxycyclopentene (3b) undergo five-membered ring opening during allylboration with 1 and 2, producing the corresponding (Z)-trienols (4a and 4b) with high stereoselectivity. 1,4-Addition of 1 and 2 to monoepoxides of 1, 3-butadiene and isoprene is favored, producing predominantly the corresponding (E)-alcohols." @default.
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- W2951223397 date "2000-11-01" @default.
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- W2951223397 title "Syntheses with Organoboranes. XI. Allylboration of Vinylic Epoxides with Allylic Dialkylboranes" @default.
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- W2951223397 doi "https://doi.org/10.1021/ol006641g" @default.
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