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• W2951238503 abstract "The Lewis acid-catalyzed intramolecular substitution reactions of 4-vinyloxy- or 4-acyloxy-azetidin-2-ones with nitrogen-bound allyl-, propargyl- and vinyl-silanes leading to the carbacephams or carbacephems, are reported. The formation of carbapenams was not observed. To illustrate the potential of these reactions to be carried out under solid-phase conditions, a synthesis of diastereomeric 5-vinyl-carbacephams via the cyclization/cleavage methodology was performed." @default.
• W2951238503 created "2019-06-27" @default.
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• W2951238503 date "2010-05-01" @default.
• W2951238503 modified "2023-10-17" @default.
• W2951238503 title "Intramolecular substitution reactions involving π-nucleophiles and N-acyliminium cations generated from azetidin-2-ones" @default.
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• W2951238503 doi "https://doi.org/10.1016/j.tet.2010.03.108" @default.
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