FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2951243134> ?p ?o ?g. }

• W2951243134 endingPage "193" @default.
• W2951243134 startingPage "181" @default.
• W2951243134 abstract "The oligo-oxamates oxamide-N,N′-bis(o-phenylene oxamic acid ethyl ester (= L1H4Et2, 5), oxamide-N,N′-bis(4,5-dimethyl-o-phenylene oxamic acid ethyl ester (= L2H4Et2Me4, 6) and oxamide-N,N′-bis(o-phenylene-N1-methyloxalamide (= L3H6Me2, 7) were used as precursor for the synthesis of the binuclear complexes [nBu4N]2[Cu2(L1)] (8), [nBu4N]2[Cu2(L2Me4)] (9), [nBu4N]2[Cu2(L3Me2)] (10), [nBu4N]2[Ni2(L1)] (11) and [nBu4N]2[Ni2(L3Me2)] (12), the trinuclear complexes [Cu3(L1)(pmdta)] (13) and [Cu3(L2Me4)(pmdta)] (14) as well as the tetranuclear complexes [Cu4(L1)(pmdta)2](NO3)2] (15), [Cu4(L2Me4)(pmdta)2](NO3)2] (16) and [Cu4(L3Me2)(pmdta)2](NO3)2] (17), (pmdta = N,N,N′,N′′,N′′-pentamethyldiethylenetriamine). The redox properties of the multinuclear complexes 8‒17 were studied by cyclic voltammetry and compared comprehensively to the ones of related mononuclear bis(oxamato), (oxamato)(oxamidato) and bis(oxamidato) complexes. The studies established further the crucial relationship between the molecular structure and the reversibility of individual redox processes and prove that unlike NiII-containing multinuclear complexes CuII ions can be reversibly oxidized when delivered in CuN3O and CuN4 coordination units. On the other hand, all here reported binuclear NiII-complexes can be reversibly reduced. Furthermore, reversible electrochemical reduction of the terminal {Cu(pmdta)}2+ fragments within 13‒17 and of [Cu(pmdta)(NO3)2] is demonstrated, providing means as new reducing agents or electron storage material." @default.
• W2951243134 created "2019-06-27" @default.
• W2951243134 creator A5015337177 @default.
• W2951243134 creator A5023056660 @default.
• W2951243134 creator A5039286027 @default.
• W2951243134 creator A5039877065 @default.
• W2951243134 creator A5056393961 @default.
• W2951243134 creator A5063410996 @default.
• W2951243134 date "2019-09-01" @default.
• W2951243134 modified "2023-10-04" @default.
• W2951243134 title "Electrochemical studies of the MI/II and MII/III (M = Ni, Cu) couples in mono- to tetranuclear complexes with oxamato/oxamidato ligands" @default.
• W2951243134 cites W1944446301 @default.
• W2951243134 cites W1968454547 @default.
• W2951243134 cites W1977864609 @default.
• W2951243134 cites W1977892176 @default.
• W2951243134 cites W1990170643 @default.
• W2951243134 cites W2001401205 @default.
• W2951243134 cites W2002863805 @default.
• W2951243134 cites W2003734110 @default.
• W2951243134 cites W2012668540 @default.
• W2951243134 cites W2019827180 @default.
• W2951243134 cites W2020539372 @default.
• W2951243134 cites W2026886923 @default.
• W2951243134 cites W2029232225 @default.
• W2951243134 cites W2031249405 @default.
• W2951243134 cites W2032153852 @default.
• W2951243134 cites W2037697241 @default.
• W2951243134 cites W2038591363 @default.
• W2951243134 cites W2039337276 @default.
• W2951243134 cites W2043753479 @default.
• W2951243134 cites W2049807213 @default.
• W2951243134 cites W2050085749 @default.
• W2951243134 cites W2051127399 @default.
• W2951243134 cites W2058555514 @default.
• W2951243134 cites W2066932188 @default.
• W2951243134 cites W2087795498 @default.
• W2951243134 cites W2109460649 @default.
• W2951243134 cites W2112319507 @default.
• W2951243134 cites W2115624436 @default.
• W2951243134 cites W2123900245 @default.
• W2951243134 cites W2131350133 @default.
• W2951243134 cites W2148651355 @default.
• W2951243134 cites W2174568887 @default.
• W2951243134 cites W2212947020 @default.
• W2951243134 cites W2283683978 @default.
• W2951243134 cites W2488055223 @default.
• W2951243134 cites W2593512427 @default.
• W2951243134 cites W2619859803 @default.
• W2951243134 cites W2704570714 @default.
• W2951243134 cites W2752945471 @default.
• W2951243134 cites W2767972313 @default.
• W2951243134 cites W2792144047 @default.
• W2951243134 cites W2805113451 @default.
• W2951243134 cites W2896991036 @default.
• W2951243134 cites W3022457912 @default.
• W2951243134 cites W4247708713 @default.
• W2951243134 doi "https://doi.org/10.1016/j.electacta.2019.06.092" @default.
• W2951243134 hasPublicationYear "2019" @default.
• W2951243134 type Work @default.
• W2951243134 sameAs 2951243134 @default.
• W2951243134 citedByCount "3" @default.
• W2951243134 countsByYear W29512431342022 @default.
• W2951243134 countsByYear W29512431342023 @default.
• W2951243134 crossrefType "journal-article" @default.
• W2951243134 hasAuthorship W2951243134A5015337177 @default.
• W2951243134 hasAuthorship W2951243134A5023056660 @default.
• W2951243134 hasAuthorship W2951243134A5039286027 @default.
• W2951243134 hasAuthorship W2951243134A5039877065 @default.
• W2951243134 hasAuthorship W2951243134A5056393961 @default.
• W2951243134 hasAuthorship W2951243134A5063410996 @default.
• W2951243134 hasConcept C147789679 @default.
• W2951243134 hasConcept C155647269 @default.
• W2951243134 hasConcept C17525397 @default.
• W2951243134 hasConcept C179104552 @default.
• W2951243134 hasConcept C185592680 @default.
• W2951243134 hasConcept C188027245 @default.
• W2951243134 hasConcept C2776210270 @default.
• W2951243134 hasConcept C2777869211 @default.
• W2951243134 hasConcept C52859227 @default.
• W2951243134 hasConcept C55904794 @default.
• W2951243134 hasConcept C71240020 @default.
• W2951243134 hasConceptScore W2951243134C147789679 @default.
• W2951243134 hasConceptScore W2951243134C155647269 @default.
• W2951243134 hasConceptScore W2951243134C17525397 @default.
• W2951243134 hasConceptScore W2951243134C179104552 @default.
• W2951243134 hasConceptScore W2951243134C185592680 @default.
• W2951243134 hasConceptScore W2951243134C188027245 @default.
• W2951243134 hasConceptScore W2951243134C2776210270 @default.
• W2951243134 hasConceptScore W2951243134C2777869211 @default.
• W2951243134 hasConceptScore W2951243134C52859227 @default.
• W2951243134 hasConceptScore W2951243134C55904794 @default.
• W2951243134 hasConceptScore W2951243134C71240020 @default.
• W2951243134 hasFunder F4320320879 @default.
• W2951243134 hasLocation W29512431341 @default.
• W2951243134 hasOpenAccess W2951243134 @default.
• W2951243134 hasPrimaryLocation W29512431341 @default.
• W2951243134 hasRelatedWork W2018266715 @default.
• W2951243134 hasRelatedWork W2060604963 @default.

• next