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- W2951250189 abstract "Abstract A new synthesis of the methyl-branched sugar axenose is described. Axenose is found in the antibiotics axenomycin, dutomycin, and polyketomycin. The synthesis is based on additions of organometallic reagents to pentodialdo-1,4-furanosides and allows the preparation of derivatives of methyl α- l -axenoside which are protected at the tertiary C-3 hydroxyl group. Conversion to thioglycoside derivatives for use in oligosaccharide synthesis was carried out directly from the methyl glycoside by treatment with phenylthiotrimethylsilane and trimethylsilyl trifluoromethanesulfonate." @default.
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- W2951250189 date "2000-01-01" @default.
- W2951250189 modified "2023-09-26" @default.
- W2951250189 title "Synthesis of phenyl 3,4-di-O-benzyl-2,6-dideoxy-3-C-methyl-1-thio-α,β-l-xylo-hexopyranoside. A glycosyl donor for axenose" @default.
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- W2951250189 doi "https://doi.org/10.1016/s0957-4166(99)00563-7" @default.
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