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• W2951257342 abstract "With KI as catalyst and m-chloroperbenzoic acid as the oxidant in acetic acid, a novel and efficient catalytic procedure has been developed for acetoxyselenenylation of alkenes, which providing a series of 2-acetoxy-1-selenenylation compounds with high regioselectivity and good yields in mild conditions. In this protocol, KI is first oxidized by m-chloroperbenzoic acid into acetylhypoiodite, which rapidly reacts with diselenide to form the active electrophilic selenenylating reagent, following an electrophilic addition of alkenes and 2-acetoxy-1-selenenylation compounds are obtained. The suitable equivalent ratio of alkene to diselenide is 1.2." @default.
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• W2951257342 date "2015-01-01" @default.
• W2951257342 modified "2023-10-02" @default.
• W2951257342 title "Novel and convenient acetoxyselenenylation of alkenes catalyzed by potassium iodide" @default.
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• W2951257342 doi "https://doi.org/10.1016/j.jorganchem.2014.10.025" @default.
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