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• W2951269677 abstract "Cyclic ammonium salts 2 were prepared by diastereoselective quaternization of nitrogen in the corresponding proline or threonine derivatives. Upon treatment with base, salts 2 underwent [1,2]- or [2,3]-shift to 3 with moderate to complete stereospecificity. The overall process entails chirality transfer from the original α carbon to the neighboring nitrogen and then back to the carbon." @default.
• W2951269677 created "2019-06-27" @default.
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• W2951269677 date "1999-05-17" @default.
• W2951269677 modified "2023-10-18" @default.
• W2951269677 title "Chirality Transfer from Carbon to Nitrogen to Carbon via Cyclic Ammonium Ylides" @default.
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• W2951269677 doi "https://doi.org/10.1021/ol9905349" @default.
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