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• W2951285334 abstract "Te-Phenyl carbamotelluroates 1 add to acetylenes under irradiation of visible light to yield β-telluroacrylamides 2 regioselectively. This reaction would be initiated by homolytic cleavage of the carbamoyl carbon−tellurium bond, producing carbamoyl and PhTe radicals. The addition reaction proceeds via a radical chain mechanism comprising two processes: (i) addition of carbamoyl radicals at the terminal carbon of the triple bond, giving vinylic radicals, and (ii) SH2 reaction on the Te atom caused by the attack of the vinyl radicals to 1." @default.
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• W2951285334 date "2001-05-24" @default.
• W2951285334 modified "2023-10-11" @default.
• W2951285334 title "Photoinduced Group Transfer Radical Addition of Carbamotelluroates to Acetylenes" @default.
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• W2951285334 doi "https://doi.org/10.1021/ol016042p" @default.
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