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• W2951291504 abstract "Abstract In this work we report for the first time the use of a carbon coated tin phosphide (Sn4P3@C) composite as the negative electrode in lithium-ion capacitor (LIC) technology. The Sn4P3@C delivers a stable capacity of ∼900 mAh g−1 vs. Li+/Li at 0.1 A g−1, with excellent capacity retention of ∼55% at 5 A g−1 (>500 mAh g−1) and ∼30% at 10 A g−1 (∼300 mAh g−1). The excellent rate capability properties of Sn4P3@C allow to combine the latter with an olive pit derived activated carbon (AC) as the positive electrode, in a 1 to 5 mass ratio, for the realization of a high energy and high power LIC. For comparison purposes a LIC using the same AC paired with hard carbon (HC), in 1 M LiPF6 EC:DMC   electrolyte, was also fabricated. At low power, the new LIC delivers 200 Wh kg−1AM (per total active mass of both electrodes), twice as much energy of its dual carbon based counterpart. The energy gain remains double until sub-minute discharge times are reached, exceeding power values of 10000 W kg−1AM. However, despite the excellent energy-to-power ratios, cyclability needs to be further improved for the viability of the technology." @default.
• W2951291504 created "2019-06-27" @default.
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• W2951291504 date "2019-09-01" @default.
• W2951291504 modified "2023-09-30" @default.
• W2951291504 title "Novel lithium-ion capacitor based on tin phosphide and olive pit derived activated carbon" @default.
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• W2951291504 doi "https://doi.org/10.1016/j.jpowsour.2019.226695" @default.
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