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- W2951294886 abstract "Abstract We developed a new approach to γ-lactols and methylene-γ-lactols based upon the radical cyclization of aluminium acetals obtained by reduction of α-bromoesters with DIBAL-H. The cyclic aluminium acetals resulting from the cyclization process could engage in situ in further functionalization, as illustrated by the Oppenauer-type oxidation to give the corresponding lactones and γ-butenolides. The preparation of butenolides using this strategy compared favourably with the direct, tin-mediated cyclization of α-bromoesters, for which side reactions such as epimerization via [1,5]-HAT processes have been observed." @default.
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- W2951294886 date "2016-02-12" @default.
- W2951294886 modified "2023-10-12" @default.
- W2951294886 title "Chemoselective access to substituted butenolides via a radical cyclization pathway: mechanistic study, limits and application" @default.
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- W2951294886 doi "https://doi.org/10.1515/pac-2015-1203" @default.
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