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- W2951309394 endingPage "1035" @default.
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- W2951309394 abstract "TiCl4-mediated aldol reactions of chiral methyl α-silyloxy ketones with a variety of aldehydes provide the corresponding 1,4-syn aldol adducts with moderate to high stereocontrol. This transformation represents a new approach to substrate-controlled acetate aldol reactions and complements the 1,4-anti asymmetric induction produced by the related α-benzyloxy ketones. This new approach could be useful in the design of more efficient syntheses of natural products." @default.
- W2951309394 created "2019-06-27" @default.
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- W2951309394 date "2015-02-01" @default.
- W2951309394 modified "2023-10-16" @default.
- W2951309394 title "Stereoselective acetate aldol reactions of α-silyloxy ketones" @default.
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- W2951309394 doi "https://doi.org/10.1016/j.tet.2014.12.099" @default.
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