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- W2951330857 abstract "Asymmetric reduction of ethyl 3-chloro-2-oxooctanoate with baker’s yeast gave ethyl 3-chloro-2-hydroxyoctanoate (3) [(2S,3R)/(2S,3S), 4:1] in 67% yield with >99% e.e. Chlorohydrin (2S,3R)-3 was converted to the titled compound in 34% total yield with 80% e.e. via the reduction, dehydrochlorination, and oxidation, successively. (2R,3R)2,3-Epoxyoctanal was also prepared from (2S,3S)-3 in 33% total yield with 94% e.e." @default.
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- W2951330857 date "1987-07-21" @default.
- W2951330857 modified "2023-09-27" @default.
- W2951330857 title "ChemInform Abstract: Asymmetric Synthesis of (2R,3S)-2,3-Epoxyoctanal, a Key Intermediate of 14,15-Leukotriene A4." @default.
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- W2951330857 doi "https://doi.org/10.1002/chin.198729330" @default.
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