Matches in SemOpenAlex for { <https://semopenalex.org/work/W2951363765> ?p ?o ?g. }
Showing items 1 to 82 of
82
with 100 items per page.
- W2951363765 endingPage "878" @default.
- W2951363765 startingPage "865" @default.
- W2951363765 abstract "A general method has been developed for the synthesis of two novel classes of heterocyclic compounds, 2,3-(or 2,7)-dihydrothiepins and 2,3-dihydro-8H-thiocins. It comprises the cycloaddition of enamine derivatives of tetrahydro-thiophen-3-ones or 4-thiacyclohexanone to activated acetylenes, e.g. dimethyl acetylenedicarboxylate, yielding bicyclic adducts, which upon thermal ring opening of the cyclobutene moiety afford the thiepin and thiocin derivatives. The enamine group in these cyclic dienamines can be hydrolysed to give stabilized enols and/or their tautomeric ketones. Peracid oxidation of the sulfur atom in the dihydrothiepins or dihydro-2H-thiocins produces the corresponding 1-oxides or 1,1-dioxides." @default.
- W2951363765 created "2019-06-27" @default.
- W2951363765 creator A5000472119 @default.
- W2951363765 creator A5045120040 @default.
- W2951363765 date "2010-09-02" @default.
- W2951363765 modified "2023-09-24" @default.
- W2951363765 title "Synthesis of thiepen and thiocin derivatives via ring enlargement" @default.
- W2951363765 cites W1974953120 @default.
- W2951363765 cites W1980504319 @default.
- W2951363765 cites W1984169960 @default.
- W2951363765 cites W1986292978 @default.
- W2951363765 cites W1991223219 @default.
- W2951363765 cites W1996159045 @default.
- W2951363765 cites W2013971948 @default.
- W2951363765 cites W2017365248 @default.
- W2951363765 cites W2019823048 @default.
- W2951363765 cites W2050145212 @default.
- W2951363765 cites W2079103491 @default.
- W2951363765 cites W2094740435 @default.
- W2951363765 cites W2325867026 @default.
- W2951363765 cites W2332748717 @default.
- W2951363765 doi "https://doi.org/10.1002/recl.19730920808" @default.
- W2951363765 hasPublicationYear "2010" @default.
- W2951363765 type Work @default.
- W2951363765 sameAs 2951363765 @default.
- W2951363765 citedByCount "20" @default.
- W2951363765 crossrefType "journal-article" @default.
- W2951363765 hasAuthorship W2951363765A5000472119 @default.
- W2951363765 hasAuthorship W2951363765A5045120040 @default.
- W2951363765 hasConcept C108204754 @default.
- W2951363765 hasConcept C111233374 @default.
- W2951363765 hasConcept C155647269 @default.
- W2951363765 hasConcept C161790260 @default.
- W2951363765 hasConcept C178790620 @default.
- W2951363765 hasConcept C185592680 @default.
- W2951363765 hasConcept C24961977 @default.
- W2951363765 hasConcept C2776011334 @default.
- W2951363765 hasConcept C2776378156 @default.
- W2951363765 hasConcept C2776568683 @default.
- W2951363765 hasConcept C2777600838 @default.
- W2951363765 hasConcept C2779664164 @default.
- W2951363765 hasConcept C2780378348 @default.
- W2951363765 hasConcept C2911029807 @default.
- W2951363765 hasConcept C518881349 @default.
- W2951363765 hasConcept C71240020 @default.
- W2951363765 hasConceptScore W2951363765C108204754 @default.
- W2951363765 hasConceptScore W2951363765C111233374 @default.
- W2951363765 hasConceptScore W2951363765C155647269 @default.
- W2951363765 hasConceptScore W2951363765C161790260 @default.
- W2951363765 hasConceptScore W2951363765C178790620 @default.
- W2951363765 hasConceptScore W2951363765C185592680 @default.
- W2951363765 hasConceptScore W2951363765C24961977 @default.
- W2951363765 hasConceptScore W2951363765C2776011334 @default.
- W2951363765 hasConceptScore W2951363765C2776378156 @default.
- W2951363765 hasConceptScore W2951363765C2776568683 @default.
- W2951363765 hasConceptScore W2951363765C2777600838 @default.
- W2951363765 hasConceptScore W2951363765C2779664164 @default.
- W2951363765 hasConceptScore W2951363765C2780378348 @default.
- W2951363765 hasConceptScore W2951363765C2911029807 @default.
- W2951363765 hasConceptScore W2951363765C518881349 @default.
- W2951363765 hasConceptScore W2951363765C71240020 @default.
- W2951363765 hasIssue "8" @default.
- W2951363765 hasLocation W29513637651 @default.
- W2951363765 hasOpenAccess W2951363765 @default.
- W2951363765 hasPrimaryLocation W29513637651 @default.
- W2951363765 hasRelatedWork W1964799889 @default.
- W2951363765 hasRelatedWork W1969151674 @default.
- W2951363765 hasRelatedWork W1984310515 @default.
- W2951363765 hasRelatedWork W2059873330 @default.
- W2951363765 hasRelatedWork W2102000009 @default.
- W2951363765 hasRelatedWork W2164468099 @default.
- W2951363765 hasRelatedWork W2409257775 @default.
- W2951363765 hasRelatedWork W2949553046 @default.
- W2951363765 hasRelatedWork W2950063136 @default.
- W2951363765 hasRelatedWork W2951363765 @default.
- W2951363765 hasVolume "92" @default.
- W2951363765 isParatext "false" @default.
- W2951363765 isRetracted "false" @default.
- W2951363765 magId "2951363765" @default.
- W2951363765 workType "article" @default.