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- W2951372548 abstract "Thermolysis or photolysis of fluoroalkanesulfonyl azides RFSO2N3 afforded the corresponding nitrene intermediates RFSO2N which reacted readily with alkanes, alkenes, benzene, dimethyl sulfide, dimethyl sulfoxide, pyridine and triphenylphosphine to give insertion or addition products. Similar results were obtained by the reactions of N, N-dichlorofluoroalkanesulfonamides, RFSO2NCl2, with the same reagents in the presence of zinc powder. Treatment of RFSO2NCl2 with alkene in the absence of zinc powder gave only a 1 : 1 adduct via a free-radical intermediate RFSO2NCl." @default.
- W2951372548 created "2019-06-27" @default.
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- W2951372548 date "2010-08-18" @default.
- W2951372548 modified "2023-09-25" @default.
- W2951372548 title "ChemInform Abstract: Synthesis and Reactions of Fluoroalkanesulfonyl Azides and N,N- Dichlorofluoroalkanesulfonamides." @default.
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- W2951372548 doi "https://doi.org/10.1002/chin.199501103" @default.
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