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- W2951413375 abstract "Herein we report an oxyboration reaction with activated substrates that employs B–O σ bond additions to C–C π bonds to form borylated isoxazoles, which are potential building blocks for drug discovery. Although this reaction can be effectively catalyzed by gold, it is the first example of uncatalyzed oxyboration of C–C π bonds by B–O σ bonds—and only the second example that is catalyzed. This oxyboration reaction is tolerant of groups incompatible with alternative lithiation/borylation and palladium-catalyzed C–H activation/borylation technologies for the synthesis of borylated isoxazoles." @default.
- W2951413375 created "2019-06-27" @default.
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- W2951413375 date "2016-06-01" @default.
- W2951413375 modified "2023-09-27" @default.
- W2951413375 title "ChemInform Abstract: Oxyboration with and Without a Catalyst: Borylated Isoxazoles via B-O σ-Bond Addition." @default.
- W2951413375 cites W2269962988 @default.
- W2951413375 doi "https://doi.org/10.1002/chin.201626201" @default.
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